Flow field of flow battery

Flow field is an important component for redox flow battery (RFB), which plays a great role in electrolyte flow and species distribution in porous electrode to enhance the mass transport. Besides, flow field structure also has a great influence in pressure drop of the battery. Download figure: Standard image High-resolution image In order to validate this concept, a lithium iron phosphate (LiFePO 4 or LFP) slurry serves as an exemplary case to showcase the potential of slurry-based flow batteries featuring a serpentine flow field and a porous carbon felt electrode design. The results reveal that incorporating a flow field significantly …

What are flow field designs used in flow batteries?

Flow field designs used in flow batteries have interested many researchers and engineers since 2012. Zawodzinski’s group first reported a vanadium flow battery (VRB) with a membrane (PEM) fuel cells. Improved limiting current density and peak power density (multiple fields where electrolyte enters a long channel packed with a porous electrode.

What is flow field design for redox flow battery (RFB)?

Prospects of flow field design for RFB have been exhibited. Flow field is an important component for redox flow battery (RFB), which plays a great role in electrolyte flow and species distribution in porous electrode to enhance the mass transport. Besides, flow field structure also has a great influence in pressure drop of the battery.

What is a flow battery?

In this innovative approach, the flow battery supplies power but its fluid also carries waste heat from the electronic devices, i.e. microprocessors. For such a flow battery with microBfabricated flow structure can output a peak power density of 0.99 W cmB2. design and (b) “flowBby” design. Redrawn from ref. 102.

Does flow field affect battery performance?

Performance excellent flow field to ensure uniform distribution of electrolytes and increases the overall performance of the battery. In order to better explore the influence of the flow field on the transmission characteristics of the electrolyte, novel variable cross-section flow field is designed to analyze its impact on battery performance.

Does flow field structure affect pressure drop of battery?

Besides, flow field structure also has a great influence in pressure drop of the battery. Better flow field not only can improve the mass transport in electrode but also is able to decrease the pressure drop of RFB.

How do interdigitated flow fields affect battery performance?

In cells with interdigitated flow fields, the increase in the number of channels results in uneven distribution of electrolyte into branch channels, which consequently leads to higher mass transport polarization. To enhance battery performance while minimizing pressure drop, several new flow field patterns have been proposed recently.

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Slurry Based Lithium-Ion Flow Battery with a Flow Field Design

Download figure: Standard image High-resolution image In order to validate this concept, a lithium iron phosphate (LiFePO 4 or LFP) slurry serves as an exemplary case to showcase the potential of slurry-based flow batteries featuring a serpentine flow field and a porous carbon felt electrode design. The results reveal that incorporating a flow field significantly …

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Scale-up of high power density redox flow batteries by …

Lab-scale redox flow batteries (RFBs) employing thinner electrodes have achieved outstandingly high power densities. When these high-performance thinner electrodes are scaled up to larger sizes required for kW-scale stacks, adding interdigitated flow fields is a simple solution in maintaining low pressure drops.

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In-plane gradient design of flow fields enables enhanced …

In the realm of redox flow batteries, the flow field plays a vital role in influencing the overall performances of the redox flow batteries. Inspired by human behavior, an in-plane gradient flow field design featuring a gradient decrease in channel width from the inlet to the outlet is proposed in this work. A three-dimensional multi-physical ...

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Investigation on flow field optimization of seawater activated battery ...

The electrolyte flow channel is one of the main components of dredging the electrolyte into the sea water to activate the battery to realize the electron transfer of positive and negative plates. However, it is not clear which form of flow channel structure will most effectively improve the flow characteristics of the electrolyte. This study proposes four flow channel …

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Flow field design and optimization based on the mass …

Subsequently, a new structure of rectangular plug flow battery (RPFB) with a plug flow field was designed and optimized according to the mass transport polarization regulation. The regulation strategy of mass transport polarization is of great significance for the performance improvement in VFBs, especially for high power density VFBs. ...

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Redox flow batteries and their stack-scale flow fields

One of the key components that impact the battery performance is the flow field, which is to distribute electrolytes onto electrodes. The design principle of flow fields is to …

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Rechargeable redox flow batteries: Flow fields, stacks …

Figure 2 (a) Schematic of a typical flow battery and (b) A detailed-diagram of cell compartment in flow batteries with a flow field design, main components include: 1-endplates, 2-current collectors, 3-graphite plates engraved with a serpentine flow field, 4-gaskets, 5-porous electrodes, and 6-ion exchange membrane. Redrawn from ref. 100.

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Numerical Simulation of Flow Field Structure of …

The performances of a vanadium redox flow battery with interdigitated flow field, hierarchical interdigitated flow field, and tapered hierarchical interdigitated flow field were evaluated through 3D numerical model.

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Optimization of flow field distribution to improve …

In the study of redox flow battery, the main purpose of designing the flow field in the flow channel is to reduce the pump power, and to the uniform supply of porous electrodes [26]. In contrast, in the BDI study, the uniformity of mass transfer at each point on the electrode determines the uniformity of current distribution and density, as ...

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Performance of a vanadium redox flow battery with and without flow fields

It is found that the battery with flow fields Exhibits 5% higher energy efficiency than the battery without flow fields, when operating at the flow rates corresponding to each battery''s maximum power-based efficiency. Therefore, the inclusion of flow fields in VRFBs can be an effective approach for improving system efficiency.

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Redox flow batteries with serpentine flow fields: Distributions …

Rechargeable redox flow batteries are considered as promising candidates for medium and large-scale stationary energy storage applications [1, 2].The electric energy stored by flow battery systems can be used to firm up intermittent renewable energy resources, and it can help to deliver consistent electricity to improve the stability of the electric grid [[3], [4], [5], [6]].

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Numerical analysis of asymmetric biomimetic flow field …

Xu et al. [7] studied the influence of different flow field structures on battery performance and showed that the serpentine flow field plays a superior role in improving the consistency of ion transport. In contrast, Zhang et al. [8] conducted a two-dimensional model study that effectively confirmed the advantages of a cross-type flow fields in reducing pressure …

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Modeling and Simulation of Vanadium Redox Flow Battery …

The fibrous electrodes used in redox flow batteries are a key component of the batteries and have a determining effect on their performance. In this work, a two-dimensional numerical model of redox flow batteries was developed and used to optimize the architecture of the electrodes employed in vanadium redox flow batteries with interdigitated flow fields.

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Effect of electrolyte convection velocity in the electrode on …

Knudsen et al. [25] studied, through flow simulations for high power redox flow batteries, serpentine flow fields (SFF) and interdigitated flow fields (IFF) in cells of active areas of 10 cm 2 and 50 cm 2 and in a cell of 400 cm 2 having an IFF. The results show that pressure loss is strongly sensitive to the electrode parameters in the case of ...

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Numerical modeling of a convection-enhanced flow field for …

More impressively, the vanadium redox flow battery with the optimized flow field achieves a higher pump-based voltage efficiency than that with the serpentine flow field (87.1% vs. 82.8%) at 150 mA cm −2, indicating that the convection-enhanced pattern shows great promise for the application in high-performance flow batteries.

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Flow field design and optimization of high power density vanadium flow ...

One of the effective strategies for developing high power density stacks is to enhance the mass transport by performing flow field design. Based on the maldistribution characteristics of concentration polarization inside a conventional rectangular flow battery (RFB), a novel trapezoid flow battery (TFB) was first proposed.

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Modeling of vanadium redox flow battery and electrode optimization with ...

The battery with a serpentine flow field achieved high energy efficiency and low pressure drop. Ionic-conducting membrane or separator is usually needed to avoid the crossover of electroactive species, which influence the voltage and coulombic efficiencies of flow batteries. The electrolyte influence the electrochemical performance notably, as ...

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Hydrodynamic analysis of flow fields for redox flow battery ...

Electrolyte flow distribution is an important factor that contributes to the performance of the overall efficiency of a redox flow battery system. In the present paper, a comparative study of the hydrodynamics of the serpentine and interdigitated flow fields has been performed. Ex situ experiments were conducted using the two flow fields in conditions typical …

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Performance characteristics of several variants of interdigitated flow ...

In a study on comparison of serpentine and interdigitated flow fields for vanadium redox flow batteries of cell area 40 cm 2 with grooved flow-channels of cross-section 3 mm × 3 mm having different rib widths 1, 2 and 3 mm, assembled with electrode compression ratio of …

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A coupled three dimensional model of vanadium redox flow battery …

Recently, Q. Xu et al. focused on numerical investigations of serpentine and parallel flow field designs of VRB cells and studied the cell performance for the different flow fields [32] pared to the two flow fields, the interdigitated flow field is a key technology to distribute electrolyte with less fluid pressure drop than the serpentine one and more efficient mass …

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Flow field design and performance analysis of vanadium redox flow battery

The main contribution of this paper are the systematic analysis of the flow field design method and the key indicators affecting battery performance, including the comparison …

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Topology Optimization of 3D Flow Fields for Flow Batteries

We consider the negative half-cell of a vanadium redox flow battery as shown in Fig. 1A. Liquid electrolyte, comprised of a solution of V 2+ and V 3+ at a concentration C inlet = 1M in 1M sulfuric acid flows in, which is then guided by the flow field toward the porous carbon-felt electrode, where the reaction V 2+ → V 3+ + e − occurs on the surfaces of electrode fibers.

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Numerical investigations of flow field designs for vanadium redox flow ...

As a key component of flow batteries, the flow field is to distribute electrolytes and to apply/collect electric current to/from cells. The critical issue of the flow field design is how to minimize the mass transport polarization at a minimum pressure drop. In this work a three-dimensional numerical model is proposed and applied to the study ...

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Design of a cobweb bionic flow field for organic redox flow battery

The mass transfer behavior and the battery performance of the redox flow battery were influenced by the electrode structure [4, 5] u et al. [6] conducted an investigation on the mass transfer and battery performance of the ORFB using three kinds of electrodes, which indicated that the sector electrode suffered the best mass transfer performance and output the …

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Elucidating effects of component materials and flow fields …

Fig. 6 shows the charge-discharge curves, efficiencies, and capacities of batteries with different flow fields at 200 mA cm −2. As shown in Fig. 6 a, when the flow rates is 7 ml min −1, the SFF-based battery delivers a lower charge overpotential than does the IFF-based battery before the charge capacity reaches 40 mAh cm −2, ...

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Topology Optimization of 3D Flow Fields for Flow Batteries

As reactant-laden electrolyte flows into the flow battery, the channels in the flow field distribute the fluid throughout the reactive porous electrode. We utilize topology …

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Rechargeable redox flow batteries: Flow fields, stacks …

batteries with flow field designs through both computational modeling and experimental

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Computational design of flow fields for vanadium redox flow batteries ...

For a given set of electrochemical conditions, it is known that the performance of battery devices depends on various factors such as material properties of the electrode [7], [8], [9] and the type of catalyst [10], [11], [12], [13] addition, the performance of VRFBs depends on mass transfer losses, where the mass transfer effect can be ameliorated by different flow fields …

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Numerical analysis of vanadium redox flow batteries …

The vanadium redox flow battery (VRB) has been widely implemented for large-scale stationary energy storge due to its safe operation, design flexibility, long life span, and high system efficiency [1].With the rapid development of VRBs, the improvement of stack performance has become a crucial task for commercialization [2].Extensive efforts have been made to …

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Dead-zone-compensated design as general …

To lessen the detrimental effects, a dead-zone-compensated design of flow field optimization is proposed. The proposed architecture allows for the detection of dead zones and their compensation on existing flow fields. Higher reactant …

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Dataset on performance of large-scale vanadium redox flow batteries ...

The dataset presented in this article are related to research articles "Effect of electrolyte convection velocity in the electrode on the performance of vanadium redox flow battery cells with serpentine flow fields" [1] and "Effect of channel dimensions of serpentine flow fields on the performance of a vanadium redox flow battery" [2].The combined dataset on the pressure …

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Investigating the coupled influence of flow fields and porous ...

Next to the impact of the flow field geometry, the properties of the porous electrode, namely its surface chemistry and microstructure, govern the flow battery performance [33].While the surface properties of the electrode determine the reaction kinetics and activation overpotentials [34], the three-dimensional structure of the electrode (here referred to as …

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DOE ESHB Chapter 6 Redox Flow Batteries

through the serpentine flow field of the electrochemical cell at the center of the figure. The flow field is commonly made from carbon and serves as the current collector as the electrolytes are oxidized and reduced. Adjacent to the flow fields reside porous carbon electrodes, maximizing the contact area with the liquid electrolyte.

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Analysis of flow field design on vanadium redox flow battery ...

This versatile tool, when properly coupled with a rigorous experimental validation of the results over a wide range of operating conditions and flow field geometries, can provide …

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